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GCSE Chemistry · Edexcel 1CH0 · Topic 1C

Ionic, covalent and metallic bonding

Key points

  • Ionic bonding: a metal transfers electrons to a non-metal, forming oppositely charged ions held by strong electrostatic forces in a giant lattice. High melting points; conduct when molten or dissolved, not when solid.
  • Ion names: -ide for simple ions (chloride), -ate for ions with oxygen (sulfate SO42−SO_4^{2-}, nitrate NO3−NO_3^-).
  • Covalent bonding: non-metal atoms share pairs of electrons. Simple molecules (e.g. water, CO₂) have weak intermolecular forces, so low melting points and no conductivity.
  • Giant covalent structures (diamond, graphite, silicon dioxide) have very high melting points. Graphite conducts because it has delocalised electrons; diamond does not. Graphene and fullerenes are other forms of carbon.
  • Metallic bonding: positive metal ions in a sea of delocalised electrons. Metals conduct and are malleable because layers can slide.
  • Each bonding model has limits, e.g. dot and cross diagrams do not show shape.

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Atoms join together by transferring or sharing electrons, and the type of bonding decides a substance's structure and properties. These notes cover ionic, covalent and metallic bonding, the main structures, and how to explain properties…

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