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GCSE Chemistry · AQA 8462 · Topic 4.6

The rate and extent of chemical change

Key points

  • The rate of reaction is how quickly reactants are used up or products are formed: mean rate = quantity ÷ time.
  • Rate increases with higher temperature, concentration or pressure, larger surface area (smaller pieces) and a catalyst.
  • Collision theory: particles must collide with at least the activation energy. More frequent or more energetic collisions mean a faster rate.
  • A catalyst speeds up a reaction by providing a pathway with lower activation energy and is not used up.
  • Reversible reactions can go both ways (⇌\rightleftharpoons). If one direction is exothermic, the other is endothermic by the same amount.
  • In a closed system a reversible reaction reaches dynamic equilibrium, where forward and reverse rates are equal.
  • (Higher) Le Chatelier's principle predicts how changing conditions shifts the position of equilibrium.

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Two questions matter for any useful reaction: how fast does it go, and how far does it go? This topic covers both: the rate of reaction and the extent of reactions that can go both ways.

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Sub-topics

  1. 4.6.1Rate of reaction
  2. 4.6.2Reversible reactions and dynamic equilibrium

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