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GCSE Chemistry · AQA 8462 · Topic 4.5.2

Chemical cells and fuel cells

Key points

  • A chemical cell contains two different metals (electrodes) in contact with an electrolyte. The bigger the difference in reactivity of the metals, the bigger the voltage.
  • A battery is two or more cells connected in series to give a larger voltage.
  • In non-rechargeable cells the reaction stops when a reactant is used up. Rechargeable cells can be reversed by applying an external current.
  • A hydrogen fuel cell is supplied with hydrogen and oxygen (from air); the hydrogen is oxidised to make electricity, and the only product is water.
  • Fuel cells: no pollutants at the point of use and no need for recharging, but hydrogen is a flammable gas that is hard to store, and producing it often uses fossil fuels.
  • (Higher) Half equations: at one electrode 2H2→4H++4e−2H_2 \rightarrow 4H^+ + 4e^-; at the other O2+4H++4e−→2H2OO_2 + 4H^+ + 4e^- \rightarrow 2H_2O.

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A chemical cell turns the energy of a chemical reaction directly into electricity. Batteries and hydrogen fuel cells both work this way. This sub-topic is chemistry only.

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